Artykuły naukowe (WEl)

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https://oa.zut.edu.pl/handle/20.500.12539/61

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Przeglądaj Artykuły naukowe (WEl) wg Temat "ester elastomers"

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  • Miniatura
    PozycjaOpen Access
    Effect of E-Beam Irradiation on Thermal and Mechanical Properties of Ester Elastomers Containing Multifunctional Alcohols
    (MDPI, 2020-05-02) Piątek-Hnat, Marta; Bomba, Kuba; Pęksiński, Jakub; Kozłowska Agnieszka; Sośnicki, Jacek G.; Idzik, Tomasz J.; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin
    The aim of this work was to investigate the thermal and mechanical properties of novel, electron beam-modified ester elastomers containing multifunctional alcohols. Polymers tested in this work consist of two blocks: sebacic acid–butylene glycol block and sebacic acid–sugar alcohol block. Di erent sugar alcohols were utilized in the polymer synthesis: glycerol, sorbitol, xylitol, erythritol, and mannitol. The polymers have undergone an irradiation procedure. The materials were irradiated with doses of 50 kGy, 100 kGy, and 150 kGy. The expected e ect of using ionizing radiation was crosslinking process and improvement of the mechanical properties. Additionally, a beneficial side e ect of the irradiation process is sterilization of the a ected materials. It is also worth noting that the materials described in this paper do not require either sensitizers or cross-linking agent in order to perform radiation modification. Radiation-modified poly(polyol sebacate-co-butylene sebacate) elastomers have been characterized in respect to the mechanical properties (quasi-static tensile tests), cross-link density, thermal properties (Di erential Scanning Calorimetry (DSC)), chemical properties: Fourier transform infrared spectroscopy (FTIR), and wettability (water contact angle). Poly(polyol sebacate-co-butylene sebacate) preopolymers were characterized with nuclear magnetic resonance spectroscopy (1HNMRand 13C NMR) and gel permeation chromatography (GPC). Thermal stability of cross-linked materials (directly after synthesis process) was tested with thermogravimetric analysis (TGA).
  • Miniatura
    PozycjaOpen Access
    Influence of e-beam irradiation on the physicochemical properties of poly(polyol succinate-co-butylene succinate) ester elastomers
    (2020-07-17) Piątek-Hnat, Marta; Bomba, Kuba; Pęksiński, Jakub; Kozłowska, Agnieszka; Sośnicki, Jacek G.; Idzik, Tomasz J.; Piwowarska, Danuta; Janik, Jolanta; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin
    The purpose of this research was synthesis and electron beam modification of novel ester elastomers consisting of sugar alcohol–succinic acid block and butylene glycol–succinic acid block. Four di erent alditols were used in the synthesis—sorbitol, erythritol, xylitol, and glycerol. The materials were irradiated with doses of 50, 100, and 150 kGy in order to determine which dose is the most beneficial. As expected, irradiation of the materials has led to the cross-link density becoming higher and improvement of the mechanical properties. Additionally, the materials were also sterilized in the process. The great advantage of elastomers described in the paper is the fact that they do not need chemical cross-linking agents or sensitizers in order to undergo radiation modification. The following tests were performed on cross-linked poly(polyol succinate-co-butylene succinate) elastomers: quasi-static tensile test, determination of cross-link density, di erential scanning calorimetry (DSC), dynamic thermomechanical analysis (DMTA), wettability (water contact angle), and Fourier transform infrared spectroscopy (FTIR). In order to confirm successful synthesis, prepolymers were analyzed by nuclear magnetic resonance spectroscopy (1H NMR and 13C NMR).
  • Miniatura
    PozycjaOpen Access
    Structure and Properties of Biodegradable Poly (Xylitol Sebacate-Co-Butylene Sebacate) Copolyester
    (MDPI, 2020-03-28) Piątek-Hnat, Marta; Bomba, Kuba; Pęksiński, Jakub; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin
    In this work, a bio-based copolyester with good mechanical properties was synthesized and characterized in terms of structure, main properties and biodegradability Determining the chemical structure of such materials is important to understand their behavior and properties. Performing an extraction of insoluble cross-linked polymer using di erent solvents allowed us to analyze how the polymer behaves when subjected to di erent chemical environments, and to obtain soluble samples suitable for more in-depth analysis. Chemical structure of poly (xylitol sebacate-co-butylene sebacate) was determined by a 1H NMR and FTIR analysis of both prepolymer gel sample and samples obtained by extraction of cross-linked polymer using di erent solvents. Block structure of the copolymer was confirmed by both NMR and DSC. Gel fraction, swelling value, water contact angle, and mechanical properties were also analyzed. Biodegradability of this material was confirmed by performing enzymatic and hydrolytic degradation. Synthesizing sugar-alcohol based copolyester using three monomers leads to obtaining a material with interesting chemical structure and desirable mechanical properties comparable to conventional elastomers.
  • Miniatura
    PozycjaOpen Access
    Tailoring the Physico-chemical Properties of Poly(xylitol-dicarboxylate-co-butylene dicarboxylate) Polyesters by Adjusting the Cross-Linking Time
    (MDPI, 2020-07-03) Piątek-Hnat, Marta; Sładkiewicz, Paulina; Bomba, Kuba; Pęksiński, Jakub; Kozłowska, Agnieszka; Sośnicki, Jacek G.; Idzik, Tomasz J.; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin; West Pomeranian University of Technology, Szczecin
    Determining the cross-linking time resulting in the best achievable properties in elastomers is a very important factor when considering their mass production. In this paper, five biodegradable polymers were synthesized—poly(xylitol-dicarboxylate-co-butylene dicarboxylate) polymers, based on xylitol obtained from renewable sources. Five di erent dicarboxylic acids with even numbers of carbon atoms in the aliphatic chain were used: succinic acid, adipic acid, suberic acid, sebacic acid, and dodecanedioic acid. Samples were taken directly after polycondensation (prepolymer samples) and at di erent stages of the cross-linking process. Physiochemical properties were determined by a gel fraction test, di erential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FTIR), quasi-static tensile tests, nuclear magnetic resonance spectroscopy (1H NMR and 13C NMR), and an in vitro biodegradation test. The best cross-linking time was determined to be 288h. Properties and degradation time can be tailored for specific applications by adjusting the dicarboxylic acid chain length.