Tailoring the Physico-chemical Properties of Poly(xylitol-dicarboxylate-co-butylene dicarboxylate) Polyesters by Adjusting the Cross-Linking Time

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dc.contributor.authorPiątek-Hnat, Marta
dc.contributor.authorSładkiewicz, Paulina
dc.contributor.authorBomba, Kuba
dc.contributor.authorPęksiński, Jakub
dc.contributor.authorKozłowska, Agnieszka
dc.contributor.authorSośnicki, Jacek G.
dc.contributor.authorIdzik, Tomasz J.
dc.contributor.organizationWest Pomeranian University of Technology, Szczecinpl_PL
dc.contributor.organizationWest Pomeranian University of Technology, Szczecinpl_PL
dc.contributor.organizationWest Pomeranian University of Technology, Szczecinpl_PL
dc.contributor.organizationWest Pomeranian University of Technology, Szczecinpl_PL
dc.contributor.organizationWest Pomeranian University of Technology, Szczecinpl_PL
dc.contributor.organizationWest Pomeranian University of Technology, Szczecinpl_PL
dc.contributor.organizationWest Pomeranian University of Technology, Szczecinpl_PL
dc.date.accessioned2023-01-27T10:12:02Z
dc.date.available2023-01-27T10:12:02Z
dc.date.issued2020-07-03
dc.description.abstractDetermining the cross-linking time resulting in the best achievable properties in elastomers is a very important factor when considering their mass production. In this paper, five biodegradable polymers were synthesized—poly(xylitol-dicarboxylate-co-butylene dicarboxylate) polymers, based on xylitol obtained from renewable sources. Five di erent dicarboxylic acids with even numbers of carbon atoms in the aliphatic chain were used: succinic acid, adipic acid, suberic acid, sebacic acid, and dodecanedioic acid. Samples were taken directly after polycondensation (prepolymer samples) and at di erent stages of the cross-linking process. Physiochemical properties were determined by a gel fraction test, di erential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FTIR), quasi-static tensile tests, nuclear magnetic resonance spectroscopy (1H NMR and 13C NMR), and an in vitro biodegradation test. The best cross-linking time was determined to be 288h. Properties and degradation time can be tailored for specific applications by adjusting the dicarboxylic acid chain length.pl_PL
dc.identifier.citationPiątek-Hnat M., Sładkiewicz P.,Bomba K., Pęksiński J., Kozłowska A., Sośnick J G., Tomasz J. Idzik T J.,(2020) Tailoring the Physico-chemical Properties of Poly(xylitol-dicarboxylate-co-butylene dicarboxylate) Polyesters by Adjusting the Cross-Linking Time”, Polymers (Basel), 12, 1493, doi:10.3390/polym12071493pl_PL
dc.identifier.doi10.3390/polym12071493
dc.identifier.urihttps://hdl.handle.net/20.500.12539/1621
dc.language.isoenpl_PL
dc.publisherMDPIpl_PL
dc.rightsUznanie autorstwa 3.0 Polska*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/pl/*
dc.sourcePolymers
dc.subjectester elastomerspl_PL
dc.subjectrenewable sourcespl_PL
dc.subjectcrosslinkingpl_PL
dc.subjectmechanical propertiespl_PL
dc.subjectbiodegradationpl_PL
dc.subject.otherDyscyplina::Nauki inżynieryjno-technicznepl_PL
dc.titleTailoring the Physico-chemical Properties of Poly(xylitol-dicarboxylate-co-butylene dicarboxylate) Polyesters by Adjusting the Cross-Linking Timepl_PL
dc.typeArticlepl_PL

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