E-Beam Effects on Poly(Xylitol Dicarboxylate-co-diol Dicarboxylate) Elastomers Tailored by Adjusting Monomer Chain Length
Ładowanie...
Data
2021-04-02
Tytuł czasopisma
ISSN czasopisma
Tytuł tomu
Wydawca
MDPI
Abstrakt
Poly(xylitol dicarboxylate-co-diol dicarboxylate) elastomers can by synthesized using
wide variety of monomers with different chain lengths. Obtained materials are all biodegradable,
thermally stable elastomers, but their specific properties like glass transition temperature, degradation
susceptibility, and mechanical moduli can be tailored for a specific application. Therefore, we
synthesized eight elastomers using a combination of two dicarboxylic acids, namely suberic and
sebacic acid, and four different diols, namely ethanediol, 1,3-propanediol, 1,4-buanediol, and 1,5-
pentanediol. Materials were further modified by e-beam treatment with a dose of 100 kGy. Materials
both before and after radiation modification were tested using tensile tests, gel fraction determination,
1H NMR, and 13C NMR. Thermal properties were tested by Differential Scanning Calorimetry (DSC),
Dynamic Thermomechanical Analysis (DMTA) and Thermogravimetric Analysis (TGA). Degradation
susceptibility to both enzymatic and hydrolytic degradation was also determined.
Opis
Słowa kluczowe
xylitol, biodegradable elastomers, radiation modification, e-beam, mechanical and thermal properties
Cytowanie
Piątek-Hnat M., Bomba K., Kowalski-Stankiewicz J P., Pęksiński, J., Kozłowska A, Sośnicki J G., Idzik T J., Schmidt B., Kowalczyk K., Walo M , Mikołajczak G., Kochmańska A.,(2021) : E-Beam Effects on Poly(Xylitol Dicarboxylate-co-diol Dicarboxylate) Elastomers Tailored by Adjusting Monomer Chain Length, Materials, 14, 1765, doi:10.3390/ma14071765