Przeglądaj wg Autor "Szewczyk, Piotr"

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    Silica-coated admixtures of bismuth and gadolinium oxides for 3D printed concrete applications: rheology, hydration, strength, microstructure, and radiation shielding perspective
    (Elsevier B.V., 2025-03-05) Sikora, Pawel; Skibicki, Szymon; Chougan, Mehdi; Szewczyk, Piotr; Cendrowski, Krzysztof; Federowicz, Karol; El-Khayatt, Ahmed M.; Saudi, H. A.; Strzałkowski, Jarosław; Abd Elrahman, Mohamed; Techman, Mateusz; Sibera, Daniel; Chung, Sang-Yeop; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; School of Mechanical, Aerospace and Civil Engineering, The University of Sheffield, Sheffield S1 3JD, UK; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University, (IMSIU), Riyadh, Saudi Arabia; Department of Physics, Faculty of Science, Al-Azhar University, Women Branch, Nasr City, Cairo, Egypt; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; Structural Engineering Department, Mansoura University, Mansoura City 35516, Egypt; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; Department of Civil and Environmental Engineering, Yonsei University, Seoul 03722, Republic of Korea
    This study examines the impact of replacing up to 5 vol% of Portland cement (PC) with both pristine mixture of Bi2O3/Gd2O3 (BG) and silica-coated BG particles. Two different types of silica coatings, each with varying synthesis methods, were applied to coat the BG structures, and their impact on the fresh, hardened, microstructure and radiation-shielding performances of the 3D printed concrete (3DPC) was investigated. Isothermal calorimetry demonstrated that pristine BG incorporation delays hydration, whereas silica coatings mitigate this, with type A coating being more effective. Early compressive strength was reduced in BG-containing mixes but normalised after seven days. Rheological tests showed that BG additives enhanced thixotropy and yield shear stresses, with 2.5 vol% being optimal, especially with method B coating. Green strength properties improved significantly with method B coated particles, showing up to 62.4 % and 57.7 % increases in strength and modulus, respectively, after 30 minutes. Micro-CT and MIP analyses confirmed reduced porosity and refined pore structure with silica coatings. Radiation shielding tests indicated superior performance in uncoated BG mixes, with method B coating providing superior shielding performance compared to that of method A coatings due to their higher surface area. In general, silica-coated BG particles enhance the mechanical, rheological, and radiation shielding properties of 3DPC, with method B coatings offering the most significant benefits.